28 Quotes by Johannes Stark
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- Author Johannes Stark
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Thus at the beginning of 1906 it seemed to be established that the emitters of the spectral series of chemical elements are their positive atomic ions.
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The spectra of atomic ions of higher valence are different from the spectra of atomic ions of the same element, but of lower valence.
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However, cases came to light later in which canal rays containing only positive ions showed a Doppler effect in the spectral lines emitted by them.
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With this in mind, for some twenty years I have set myself as my particular task the experimental investigation of the connexion between change in the structure and change in the spectra of chemical atoms.
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We have learnt through experience that when an electrical ray strikes the surface of an atom, an electron, and in some circumstances a second and even a third electron, can be detached.
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Moreover, the abundance of chemical compounds and their importance in daily life hindered the chemist from investigating the question, in what does the individuality of the atoms of different elements consist.
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We can in fact first place the beam of rays of moving positive atomic ions in a plane perpendicular to the axis in which we see the spectral lines emitted by them.
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By allowing the positive ions to pass through an electric field and thus giving them a certain velocity, it is possible to distinguish them from the neutral, stationary atoms.
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Along a series of lines running from longer to shorter wavelengths the effect of the electric field becomes greater as the serial numbers increase - that is, as the wavelength decreases.
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